Synthesis and characterization of new metal-free and metallophthalocyanines containing spherical or cylindrical macrotricyclic moieties

Bilgin A., Ertem B., Gok Y.

POLYHEDRON, cilt.24, sa.10, ss.1117-1124, 2005 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 24 Sayı: 10
  • Basım Tarihi: 2005
  • Doi Numarası: 10.1016/j.poly.2005.01.025
  • Dergi Adı: POLYHEDRON
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1117-1124
  • Anahtar Kelimeler: phthalocyanine, cylindrical or spherical macrocycle, template effect, transition metal, macropolycyclization, isoindolinediimme, FREE PHTHALOCYANINE, UNSYMMETRICAL PHTHALOCYANINE, COPPER(II) PHTHALOCYANINES, COMPLEXES, DERIVATIVES, RECEPTORS, CHEMISTRY, COBALT, ROUTE
  • Karadeniz Teknik Üniversitesi Adresli: Evet

Özet

New metal-free phthalocyanines (8-9) fused in peripheral positions with four tetraazadithiahexaoxa supercryptands were synthesized by tricyclotetramerization of isoindolinediimine derivatives of supercryptands (6-7). Metallophthalocyanines (10-11) were prepared by the reaction of the metal-free phthalocyanines with metal salts or cyclotetramerization of dicyano compounds (4-5) and anhydrous salts of some transition metal chlorides. The novel compounds were characterized by elemental analyses, IR, H-1 and C-13 NMR, UV-Vis and MS spectral data (c) 2005 Elsevier Ltd. All rights reserved.