Influence of Chemical Effect on the K-beta/K-alpha Intensity Ratios and K-beta Energy Shift of Co, Ni, Cu, and Zn Complexes

APAYDIN G., AYLIKCI V., BIYIKLIOĞLU Z., TIRAŞOĞLU E., KANTEKİN H.

CHINESE JOURNAL OF CHEMICAL PHYSICS, cilt.21, sa.6, ss.591-595, 2008 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 21 Sayı: 6
  • Basım Tarihi: 2008
  • Doi Numarası: 10.1088/1674-0068/21/06/591-595
  • Dergi Adı: CHINESE JOURNAL OF CHEMICAL PHYSICS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.591-595
  • Karadeniz Teknik Üniversitesi Adresli: Evet

Özet

Chemical effects on the K-beta/K-alpha intensity ratios and Delta E energy differences for Co, Ni, Cu, and Zn complexes were investigated. The samples were excited by 59.5 keV gamma-rays from a Am-241 annular radioactive source. K X-rays emitted by samples were counted by an Ultra-LEGe detector with a resolution of 150 eV at 5.9 keV. We observed the effects of different ligands on the K-beta/K-alpha intensity ratios and Delta E energy differences for Co, Ni, Cu, and Zn complexes. We tried to investigate chemical effects on central atoms using the behaviors of different ligands in these complexes. The experimental values of K-beta/K-alpha were compared with the theoretical and other experimental values of pure Co, Ni, Cn, and Zn.