Synthesis and characterization of a new organo-soluble metal-free and metallophthalocyanines bearing flexible moieties

Nas A., Kantekin H.

POLYHEDRON, cilt.30, sa.6, ss.1085-1090, 2011 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 30 Sayı: 6
  • Basım Tarihi: 2011
  • Doi Numarası: 10.1016/j.poly.2011.01.005
  • Dergi Adı: POLYHEDRON
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1085-1090
  • Anahtar Kelimeler: 1,2-Dihydroacenaphthylen-1-ol, Metallophthalocyanine, Microwave-assisted, 4-Nitrophthalonitrile, Thermal stability, PHOTODYNAMIC THERAPY, PHTHALOCYANINE, PORPHYRINS, BEHAVIOR, PDT
  • Karadeniz Teknik Üniversitesi Adresli: Evet

Özet

This paper describes a new symmetric metal-free phthalocyanine and its transition metal complexes which were prepared by a condensation of 1,2-dihydroacenaphthylen-1-ol 1 and 4-nitro phthalonitrile 2 with Co(II), Ni(II), Cu(II), and Zn(II) salts in 2-(dimethylamino)ethanol, respectively. The novel phthalocyanines bearing oxygen donor atoms on peripheral position have been characterized by IR, UV-Vis, H-1 NMR, C-13 NMR, Mass spectra and elemental analysis. The thermal behaviours of 4-8 were investigated by TG/DTA. (C) 2011 Elsevier Ltd. All rights reserved.