Microwave-assisted synthesis and characterization of novel metal-free and metallophthalocyanines containing four 13-membered dithiadiaza macrocycles

Kantekin H., BIYIKLIGLU Z.

DYES AND PIGMENTS, cilt.77, sa.1, ss.98-102, 2008 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 77 Sayı: 1
  • Basım Tarihi: 2008
  • Doi Numarası: 10.1016/j.dyepig.2007.03.012
  • Dergi Adı: DYES AND PIGMENTS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.98-102
  • Anahtar Kelimeler: phthalocyanine, dithiadiazamacrocycle, phthalonitrile, macrocyclization, tosylation, PHTHALOCYANINE DERIVATIVES, PENTANUCLEAR COMPLEXES, COPPER PHTHALOCYANINE, INCLUSION COMPLEXES, PORPHYRINS, MOIETIES, LIGANDS, DESIGN, MONO
  • Karadeniz Teknik Üniversitesi Adresli: Evet

Özet

Novel, tetrasubstituted metal-free phthalocyanine and metallophtalocyanines bearing four 13-membered dithiadiaza. macrocycle peripheral groups were synthesized by cyclotetramerization of the phthalonitrile derivative in a multi-step reaction sequence, The new compounds were characterized by a combination of IR, H-1 NMR, C-13 NMR, UV-vis, elemental analysis and MS spectral data. (C) 2007 Elsevier Ltd. All rights reserved.