Synthesis of a new macromonomeric peroxyinitiator having poly(tetrahydrofuran) units


Savaskan S., Hazer B.

ANGEWANDTE MAKROMOLEKULARE CHEMIE, cilt.239, ss.13-26, 1996 (SCI İndekslerine Giren Dergi) identifier

  • Cilt numarası: 239
  • Basım Tarihi: 1996
  • Doi Numarası: 10.1002/apmc.1996.052390102
  • Dergi Adı: ANGEWANDTE MAKROMOLEKULARE CHEMIE
  • Sayfa Sayıları: ss.13-26

Özet

A new macromonomeric peroxyinitiator (MMPI) was synthesized by the reaction of polytetrahydrofurandiol (p-THF-diol), M(w) 1000), isophorone diisocyanate, 2,5-dimethylhexyl-2,5-dihydroperoxide and 2-isocyanatoethyl methacrylate. Homopolymerization of MMPI at 80 degrees C gave crosslinked polytetrahydrofuran (poly-THF) with swelling ratios in CHCl3 varying between 1.4 and 4.2.