Synthesis and characterization of octakis(4,5-bis{2-[2-(1-naphthyloxy)ethoxy]ethoxy})- substituted metal-free and metallophthalocyanines

KARADENIZ H., ACAR İ., BIYIKLIOĞLU Z., AĞIN F., KANTEKİN H.

JOURNAL OF COORDINATION CHEMISTRY, vol.63, no.8, pp.1411-1417, 2010 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 63 Issue: 8
  • Publication Date: 2010
  • Doi Number: 10.1080/00958971003754540
  • Journal Name: JOURNAL OF COORDINATION CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.1411-1417
  • Keywords: Synthesis, Cyclotetramerization, 4, 5-Dichlorophthalonitrile, Microwave irradiation, SULFONATED PHTHALOCYANINES, OPTICAL-ABSORPTION, COPPER
  • Karadeniz Technical University Affiliated: Yes

Abstract

The synthesis of octakis(4,5-bis{2-[2-(1-naphthyloxy)ethoxy]ethoxy}) metal-free (4) and metallophthalocyanines (5-8) were carried out by the cyclotetramerization of a 4,5-bis{2-[2-(1-naphthyloxy)ethoxy]ethoxy}phthalonitrile (3). Newly substituted octakisphthalocyanines showed enhanced solubility in organic solvents. The new compounds were characterized by IR, 1H-NMR, 13C-NMR, UV-Vis, and MS spectral data.