Synthesis and characterization of octakis(4,5-bis{2-[2-(1-naphthyloxy)ethoxy]ethoxy})- substituted metal-free and metallophthalocyanines

KARADENIZ H., ACAR İ., BIYIKLIOĞLU Z., AĞIN F., KANTEKİN H.

JOURNAL OF COORDINATION CHEMISTRY, cilt.63, sa.8, ss.1411-1417, 2010 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 63 Sayı: 8
  • Basım Tarihi: 2010
  • Doi Numarası: 10.1080/00958971003754540
  • Dergi Adı: JOURNAL OF COORDINATION CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1411-1417
  • Anahtar Kelimeler: Synthesis, Cyclotetramerization, 4, 5-Dichlorophthalonitrile, Microwave irradiation, SULFONATED PHTHALOCYANINES, OPTICAL-ABSORPTION, COPPER
  • Karadeniz Teknik Üniversitesi Adresli: Evet

Özet

The synthesis of octakis(4,5-bis{2-[2-(1-naphthyloxy)ethoxy]ethoxy}) metal-free (4) and metallophthalocyanines (5-8) were carried out by the cyclotetramerization of a 4,5-bis{2-[2-(1-naphthyloxy)ethoxy]ethoxy}phthalonitrile (3). Newly substituted octakisphthalocyanines showed enhanced solubility in organic solvents. The new compounds were characterized by IR, 1H-NMR, 13C-NMR, UV-Vis, and MS spectral data.