trans-Bis(diethanolamine)bis(isothio-cyanato)nickel(II)

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Atıf İçin Kopyala

YILMAZ V. T., KARADAĞ A., Thone C., Herbst-Irmer R.

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, cilt.56, ss.948-949, 2000 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 56
• Basım Tarihi: 2000
• Doi Numarası: 10.1107/s0108270100007289
• Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Sayfa Sayıları: ss.948-949
• Karadeniz Teknik Üniversitesi Adresli: Hayır

Özet

In the neutral title complex, trans-bis(2,2'-iminodiethanol-N,O)bis(isothiocyanato)nickel(II), [Ni(NCS)(2)(C4H11NO2)(2)], the isothiocyanate ions and the diethanolamine molecules act as monodentate and bidentate ligands, respectively. The Ni-II ion exhibits a distorted octahedral configuration with crystallographically imposed inversion symmetry and N-NCS- Ni-N-amine and N-NCS -Ni-O-amine bond angles of 88.78 (10) and 89.44 (10)degrees, respectively. The Ni-N bond distances are in the range 2.069 (3)-2.096 (2) Angstrom. The molecules are linked by hydrogen bonds to form a three-dimensional infinite lattice.