Influence of chemical effect on the K-shell X-ray production cross-sections and radiative Auger ratios of Zn complexes

AYLIKCI V., BIYIKLIOĞLU Z., CENGIZ E., AYLIKCI N. K., APAYDIN G., AKSOY C., ...More

CHEMICAL PHYSICS, vol.365, no.3, pp.144-149, 2009 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 365 Issue: 3
  • Publication Date: 2009
  • Doi Number: 10.1016/j.chemphys.2009.10.007
  • Journal Name: CHEMICAL PHYSICS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.144-149
  • Karadeniz Technical University Affiliated: Yes

Abstract

In this study, sigma(K alpha), sigma(K beta) production cross-sections, KLM/K(alpha) and KMM/K(beta) radiative Auger intensity ratios of Zn in different complexes were measured. The samples were excited by 59.5 keV gamma-rays from a (241)Am annular radioactive source. K X-rays emitted by samples were counted by an Ultra-LEGe detector with a resolution of 150 eV at 5.9 keV. The charge transfer effects on central Zn atom was investigated by using the behaviors of different ligands in these complexes. (C) 2009 Elsevier B. V. All rights reserved.