Production of Al2024/h-BN nanocomposites with improved corrosion, wear and mechanical properties


KARABACAK A. H., ÇANAKÇI A., ÇELEBİ M., GÜLER O., TUNÇ S. A., Arpacı K. A.

Materials Chemistry and Physics, vol.300, 2023 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 300
  • Publication Date: 2023
  • Doi Number: 10.1016/j.matchemphys.2023.127566
  • Journal Name: Materials Chemistry and Physics
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Chemical Abstracts Core, Communication Abstracts, INSPEC, Metadex, Civil Engineering Abstracts
  • Keywords: Al2024, Corrosion, h-BN, Powder metallurgy, Wear
  • Karadeniz Technical University Affiliated: Yes

Abstract

In this study, hexagonal boron nitride (h-BN) reinforced Al-based metal matrix nanocomposites were successfully prepared using a powder metallurgy-assisted high-energy ball milling and vacuum-hot pressing process. Al2024 alloy and h-BN nano-powders (at 0, 2, 3, 4, and 5wt%) were milled for 8 h to produce Al2024/h-BN nanocomposites. The effect of h-BN nanoparticle content on the microstructure, density, hardness, tensile strength, wear, and corrosion behavior of Al2024/h-BN nanocomposites was investigated. It was observed that the h-BN powders in the Al2024/h-BN nanocomposites were homogeneously distributed up to a content of 4 wt%, beyond which the h-BN aggregated at the grain boundaries due to excessive reinforcement. The uniform distribution of h-BN nanoparticles in the Al2024 matrix had a positive effect on the mechanical properties and wear and corrosion behavior of the Al2024/h-BN nanocomposites. The results showed that the highest values of hardness and tensile strength were 126 HB and 299.72 MPa, respectively, in the 4 wt% h-BN reinforced sample. The wear volume loss decreased significantly as the h-BN reinforcement content increased up to 4 wt %. The corrosion experiment results showed that the corrosion resistance of the 4 wt % h-BN reinforced nanocomposite, which had the lowest polarization resistance of 15.22 Ω cm2, was almost 5 times higher than that of the unreinforced Al2024 alloy.