SYNTHESIS OF EPICHLOROHYDRIN METHYL-METHACRYLATE BLOCK-COPOLYMERS VIA ACTIVATED MONOMER-TO-PHOTO INITIATED FREE-RADICAL MECHANISM


CAKMAK I.

JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, pp.167-173, 1995 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume:
  • Publication Date: 1995
  • Doi Number: 10.1080/10601329508020325
  • Title of Journal : JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY
  • Page Numbers: pp.167-173

Abstract

Epiclorohydrin(ECH) was polymerized by an activated monomer mechanism (AM) in the presence of N,N'-diethyl-N,N'-bis(2-hydroxy ethyl) thiuram disulfide(DHTD). Poly(epichlorohydrin) (PECH) possessing thiuram disulfide group in the main chain thus obtained was used in the photo induced polymerization of methyl methacrylate to yield PECH-PMMA block capolymers. Characterization of block copolymers was carried out by spectroscopic methods.