SYNTHESIS OF EPICHLOROHYDRIN METHYL-METHACRYLATE BLOCK-COPOLYMERS VIA ACTIVATED MONOMER-TO-PHOTO INITIATED FREE-RADICAL MECHANISM


CAKMAK I.

JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, ss.167-173, 1995 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası:
  • Basım Tarihi: 1995
  • Doi Numarası: 10.1080/10601329508020325
  • Dergi Adı: JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY
  • Sayfa Sayıları: ss.167-173

Özet

Epiclorohydrin(ECH) was polymerized by an activated monomer mechanism (AM) in the presence of N,N'-diethyl-N,N'-bis(2-hydroxy ethyl) thiuram disulfide(DHTD). Poly(epichlorohydrin) (PECH) possessing thiuram disulfide group in the main chain thus obtained was used in the photo induced polymerization of methyl methacrylate to yield PECH-PMMA block capolymers. Characterization of block copolymers was carried out by spectroscopic methods.