First example of a vic-dioxime and its homo- and heteropentanuclear complexes containing a macrobicyclic moiety

GOK Y., Ocak U. , SENTURK H. B.

NEW JOURNAL OF CHEMISTRY, vol.25, no.3, pp.364-368, 2001 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Letter
  • Volume: 25 Issue: 3
  • Publication Date: 2001
  • Doi Number: 10.1039/b004624h
  • Title of Journal : NEW JOURNAL OF CHEMISTRY
  • Page Numbers: pp.364-368


The novel N,N'-substituted diaminoglyoxime (H2L) containing a diazadioxadithiacyclo macrobicycle has been synthesized from an aromatic primary amine containing a cryptand unit and (E,E)-dichloroglyoxime. The homopentanuclear nickel(II) and heteropentanuclear complexes of dioxime were obtained.