Microwave-assisted synthesis and characterization of a new metal-free and metallophthalocyanines


KILICASLAN M. B. , AĞIN F. , KANTEKİN H.

JOURNAL OF COORDINATION CHEMISTRY, vol.63, no.5, pp.861-867, 2010 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 63 Issue: 5
  • Publication Date: 2010
  • Doi Number: 10.1080/00958971003645953
  • Title of Journal : JOURNAL OF COORDINATION CHEMISTRY
  • Page Numbers: pp.861-867

Abstract

Dinitrile monomer (3) was synthesized by nucleophilic aromatic substitution of 4-phenoxyphenol (1) with 4-nitrophthalonitrile (2). The metal-free phthalocyanine (4) was prepared by the reaction of dinitrile monomer (3) with DMAE. Ni(II), Co(II), and Zn(II) metallophthalocyanines were prepared by the reaction of 3 with chlorides of Ni(II), Co(II), and Zn(II) in DMAE. The new compounds were characterized by IR, 1H- and 13C-NMR, UV-Vis, elemental analysis, and MS specral data.