Microwave-assisted synthesis and characterization of a new metal-free and metallophthalocyanines

Sağlam M. B., Ağın F., Kantekin H.

JOURNAL OF COORDINATION CHEMISTRY, cilt.63, sa.5, ss.861-867, 2010 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 63 Sayı: 5
  • Basım Tarihi: 2010
  • Doi Numarası: 10.1080/00958971003645953
  • Dergi Adı: JOURNAL OF COORDINATION CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.861-867
  • Karadeniz Teknik Üniversitesi Adresli: Evet

Özet

Dinitrile monomer (3) was synthesized by nucleophilic aromatic substitution of 4-phenoxyphenol (1) with 4-nitrophthalonitrile (2). The metal-free phthalocyanine (4) was prepared by the reaction of dinitrile monomer (3) with DMAE. Ni(II), Co(II), and Zn(II) metallophthalocyanines were prepared by the reaction of 3 with chlorides of Ni(II), Co(II), and Zn(II) in DMAE. The new compounds were characterized by IR, 1H- and 13C-NMR, UV-Vis, elemental analysis, and MS specral data.