Electrochemical and in situ spectroelectrochemical properties of metal-free and metallophthalocyanines containing alpha-naphtholbenzein groups on the peripheral positions


SAĞLAM M. B. , ÖZKAYA A. R.

TRANSITION METAL CHEMISTRY, cilt.41, ss.605-612, 2016 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 41 Konu: 5
  • Basım Tarihi: 2016
  • Doi Numarası: 10.1007/s11243-016-0059-y
  • Dergi Adı: TRANSITION METAL CHEMISTRY
  • Sayfa Sayıları: ss.605-612

Özet

Phthalocyanine (Pc) compounds-containing alpha-naphtholbenzein units have been synthesized and characterized by spectroscopic data and elemental analysis. The redox properties of the compounds were investigated by cyclic and square wave voltammetry, controlled-potential coulometry and in situ spectroelectrochemistry in DMSO and compared with the free phthalonitrile ligand. The Pc compounds displayed common metal and/or ring-based reduction and oxidation processes. However, electrochemical measurements clearly suggested that the substituents involving anthraquinone units are redox active and so have a considerable effect on the redox processes of these compounds.