Synthesis and characterization of new metal-free and metallophthalocyanines substituted with tetrathiadiazamacrobicyclic moieties

Gok Y., Kantekin H., Degirmencioglu I.

SUPRAMOLECULAR CHEMISTRY, cilt.15, sa.5, ss.335-343, 2003 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 15 Sayı: 5
  • Basım Tarihi: 2003
  • Doi Numarası: 10.1080/1061027031000088076
  • Dergi Adı: SUPRAMOLECULAR CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.335-343
  • Anahtar Kelimeler: phthalocyanine, tetrathiadiazamacrobicycle, template effect, macrocyclization, cryptand, CRYSTAL-STRUCTURE, INFRARED-SPECTRA, PHTHALOCYANINE DERIVATIVES, ELECTROCHEMICAL PROPERTIES, COPPER PHTHALOCYANINE, CROWN, COMPLEXES, SPECTROSCOPY, CHEMISTRY, SILVER(I)
  • Karadeniz Teknik Üniversitesi Adresli: Evet

Özet

New metal-free (5, 8) and metallophthalocyanines (6, 9) containing four diazatetrathiamacrobicycles or crosswise-disubstituted attached with two nitro and two macrobicyclic groups were synthesized by cyclotetramerization of 7,8-dicyano-4,11,22,23-tetrathia-1,14-diazapentacyclo[12.10.10.0(5,10).0(16,21).0(26,31)]tetratriconta-5,7,12,19,20,21, 28 30,32-nonane (3), 8,10-dihydro-8,11-diimino-4,14, 24 34,-tetrathia-1,17-diazapentacyclo[15.13.13.0(5,13).0(19,23).0(28,33)]tetratriconta-5,7,12,19,20,22,28,30,32-nonaisoiminoindoline (4) or 6-nitro-1,3,3-trichloroisoindolenine (7) in the presence of the corresponding metal salt or a strong organic base. The new compounds were characterized by a combination of elemental analysis and H-1 NMR, C-13 NMR, IR, UV-Vis and MS spectral data.