trans-Tetraaquabis(p-nitrobenzoxasulfamato)cobalt(II)

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Atıf İçin Kopyala

Kazak C., Yazicilar T., YILMAZ V. T.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.60, 2004 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 60
• Basım Tarihi: 2004
• Doi Numarası: 10.1107/s1600536804006336
• Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Karadeniz Teknik Üniversitesi Adresli: Hayır

Özet

The structure of the title complex consists of neutral molecules of [Co(nbs)(2)(H2O)(4)] (nbs is the p-nitrobenzoxasulfamate anion, C6H3N2O5S-). The Co2+ ion occupies an inversion centre and exhibits a distorted octahedral geometry, involving two monodentate nbs (N-imine) anions and four water molecules. The crystal structure is stabilized by hydrogen bonding and weak aromatic pi-pi stacking interactions between the benzene rings of nbs ligands, forming a three-dimensional network.