Synthesis and characterization of novel phthalocyanines peripherally fused to four 20-membered tetraaza-dioxamacro cycles


Gok Y., Yildiz S.

POLYHEDRON, cilt.16, ss.113-117, 1997 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 16 Konu: 1
  • Basım Tarihi: 1997
  • Doi Numarası: 10.1016/0277-5387(96)00235-5
  • Dergi Adı: POLYHEDRON
  • Sayfa Sayıları: ss.113-117

Özet

New metal-free 3 and metallophthalocyanines 4-5 (M = Ni or Zn) substituted with four 20-membered tetraaza-dioxa macrocycles from 21,22-dicyano-2,8,11,17-tetra-(toluene-p-sulfonyl)-1,2,3,4,5,6,7,8,9,10,11, 12,13,14,15,16,17,18-octadecahydrox[l] [2,8,11,17]tetraaza [4,13]dioxadicontine (2) are described. Cyclotetramerization of the substituted phthalonitrile (2) leads to a product very soluble in common organic solvents. The characterization of the compounds was accomplished by elemental analysis, H-1,C-13 NMR, IR, UV-vis and MS spectral data. Copyright (C) 1996 Published by Elsevier Science Ltd