Defect-induced room temperature ferromagnetism in B-doped ZnO
CERAMICS INTERNATIONAL, cilt.39, sa.4, ss.4609-4617, 2013 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 39 Sayı: 4
- Basım Tarihi: 2013
- Doi Numarası: 10.1016/j.ceramint.2012.11.060
- Dergi Adı: CERAMICS INTERNATIONAL
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.4609-4617
- Anahtar Kelimeler: ZnO:B, Photoluminescence, Ferromagnetism, First-principle calculation, THIN-FILMS, OPTICAL-PROPERTIES, MICROSTRUCTURE, TRANSITION, FABRICATION, EXCHANGE
- Açık Arşiv Koleksiyonu: AVESİS Açık Erişim Koleksiyonu
- Karadeniz Teknik Üniversitesi Adresli: Evet
Özet
ZnO microrods were grown on glass substrates by the spray pyrolysis method and boron was doped into the ZnO microrods by diffusion. X-ray diffraction results confirmed that the incorporation of B leads to a slight reduction in the deposit texture. Scanning electron microscopy measurements showed that the morphology of the ZnO samples changed from a microrod to nanocrystalline structure with B-doping. Photoluminescence data indicate that B-doping leads to a relative increase of the unstructured green band intensity. Magnetic measurements revealed that B-doped ZnO samples exhibited room temperature ferromagnetism related to defects, in agreement with first principles theoretical calculations. (C) 2012 Elsevier Ltd and Techna Group S.r.l. All rights reserved.