The synthesis and characterization of novel copper(II) phthalocyanines substituted with four 17-membered macrocyclic ionophores


Gok Y., Yildiz S.

POLYHEDRON, vol.16, no.14, pp.2335-2339, 1997 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 16 Issue: 14
  • Publication Date: 1997
  • Doi Number: 10.1016/s0277-5387(96)00593-1
  • Title of Journal : POLYHEDRON
  • Page Numbers: pp.2335-2339

Abstract

Copper(II) phthalocyanine containing four 17-membered dioxa-triaza macrocycles has been synthesized starting from copper(II) phthalocyanine substituted 1,2-bis(ethoxycarbonylmetoxy) and 3,3'-diaminodipropylamine. This copper(II) phthalocyanine was used in the extraction of alkali metals and alkaline earth metal picrates from aqueous media. The structures of the compounds are proposed according to elemental analysis, H-1,C-13 NMR, IR, UV-VIS and MS spectral data. (C) 1997 Elsevier Science Ltd.