Optimization of parameters with experimental design for the adsorption of mercury using polyethylenimine modified-activated carbon

Saleh T. A., SARI A., TÜZEN M.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, cilt.5, sa.1, ss.1079-1088, 2017 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 5 Sayı: 1
  • Basım Tarihi: 2017
  • Doi Numarası: 10.1016/j.jece.2017.01.032
  • Dergi Adı: JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Emerging Sources Citation Index (ESCI), Scopus, CAB Abstracts, Chemical Abstracts Core, Compendex, INSPEC, Veterinary Science Database
  • Sayfa Sayıları: ss.1079-1088
  • Anahtar Kelimeler: Polyethylenimine, Activated carbon, Adsorption, Hg(II), Factorial design, Kinetics and thermodynamics, AQUEOUS-SOLUTION, REMOVAL, HG(II), EQUILIBRIUM, SORPTION, DESULFURIZATION, BIOSORPTION, ADSORBENT, TIRES, BATCH
  • Karadeniz Teknik Üniversitesi Adresli: Evet

Özet

This study reports a facile hydrothermal method to synthesize polyethylenimine-modified activated carbon derived from waste tires ( PEI-AC). The obtained material was characterized by Fourier transform infrared spectroscopy ( FTIR), Scanning Electron microscopy ( SEM) equipped with Energy-Dispersive Xray spectroscopy ( EDX), Thermogravimetric analyzer ( TGA), and Brunauer-Emmett-Teller ( BET) analyzer. The adsorption efficiency of the new adsorbent for the removal of Hg(II) was evaluated under the effects of its concentration, temperature, adsorption contact time, medium pH and re-usability. The optimum experimental conditions were found under response surface methodology ( RSM)using central composite design ( CCD). The results of the study show very good adsorption performance and high regeneration efficiency; the adsorption data fitted well into pseudo-second order model. The Langmuir monolayer capacity was determined to be 16.39 mg g (1). The exothermic enthalpy change ( DH) of 24.65 kJ mol (1) and negative Gibbs free energy change ( DG) assured the viability of the adsorption process. Therefore, the material leverages its cheap source and ease of regeneration in combination with its high and fast uptake capacities to offer a great promise for wastewater remediation. (C) 2017 Elsevier Ltd. All rights reserved.