Synthesis and electrochemistry of phthalocyanines bearing [(3,4-dimethoxybenzyl) oxy] groups


Omeroglu I., BIYIKLIOĞLU Z.

TURKISH JOURNAL OF CHEMISTRY, vol.39, no.2, pp.347-358, 2015 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 39 Issue: 2
  • Publication Date: 2015
  • Doi Number: 10.3906/kim-1408-71
  • Journal Name: TURKISH JOURNAL OF CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, TR DİZİN (ULAKBİM)
  • Page Numbers: pp.347-358
  • Karadeniz Technical University Affiliated: Yes

Abstract

In this study peripherally tetra-substituted metal-free, metallophthalocyanines bearing (3,4-dimethoxybenzyl) oxy groups have been synthesized and characterized. Electrochemical properties of novel phthalocyanines 4, 5, 6, and 7 were determined by cyclic and square wave voltammetry in order to define their possible applications in different electrochemical technologies. Co-II and (TiO)-O-IV metal ions behave as redox active cations in the core of the CoPc and TiOPc complexes, respectively. Voltammetric studies revealed that phthalocyanines have reversible/irreversible redox processes, which are the main requirement for the technological usage of these compounds.