Solid phase extraction of copper(II) by modified octadecyl silica membrane disks with 3-{2-[2-(2-hydroxyimino-1-methyl-propylideneamino)-ethylamino]-ethyl-imino}-butan-2-one oxime

Dalman O., Karabocek S., Demirak A., Tufekci M.

TURKISH JOURNAL OF CHEMISTRY, cilt.27, sa.5, ss.649-656, 2003 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 27 Sayı: 5
  • Basım Tarihi: 2003
  • Dergi Adı: TURKISH JOURNAL OF CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, TR DİZİN (ULAKBİM)
  • Sayfa Sayıları: ss.649-656
  • Karadeniz Teknik Üniversitesi Adresli: Evet

Özet

A simple, selective and rapid method for determining trace amounts of copper(II) ions in various types of water samples using atomic absorption spectrophotometry was investigated. Copper(II) ions from water samples were preconcentrated by solid phase extraction rising octadecyl silica membrane disks modified with 3-{2-[2-(2-Hydroxyimino-1-methyl-propylideneamino)-ethylamino]-ethyl-imino}-butan-2-one oxime, (H(2)mdo). The experimental conditions were optimized by changing several parameters such as volume of eluting solvent, the effect of pH, eluent flow rates, the amount of H2mdo, breakthrough the volume, limit of detection and maximum capacity of the disks for Cu2+ recovery. The method was applied to the recovery of Cu(II) ions from seven different water samples and ail international certified reference sample (SLRS-4), the method was also quantitative.