Two new polyamidoximes having appropriate functions to bind transition metal ions such as Ni(II) and Pd(II) were prepared. Polymers were obtained by the reactions of (E,E)-dichloroglyoxime with new aromatic primary amines. Polymers and their complexes were characterized by elemental analyses, i.r. and H-1-NMR spectra, DSC, and electrical conductivity measurements. The molecular weights of polymers were determined by light scattering technique.