The semi-empirical determination of KLL Auger, K-alpha 1 and K-alpha 2 X-ray line widths for sulfur atom in new 1,2,4-triazol compounds containing thiophene ring


AYLIKCI N. K. , Sancak K., Aylikci V., Tirasoglu E. , Unluer D., Depci T.

CHEMICAL PHYSICS LETTERS, vol.706, pp.40-46, 2018 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 706
  • Publication Date: 2018
  • Doi Number: 10.1016/j.cplett.2018.05.070
  • Title of Journal : CHEMICAL PHYSICS LETTERS
  • Page Numbers: pp.40-46

Abstract

In this study K-alpha 1, K-alpha 2 and KLL Auger line widths were determined semi-empirically by using K shell fluorescence yields of sulfur even if K-alpha X-ray lines cannot be resolved in our detector system. The samples of 1,2,4-Triazoles were irradiated by an annular 50 mCi Fe-55 radioactive source. It was found that halogens (e.g. Cl) and electron donating groups (e.g. -CH3, -OCH3, -OH etc.) have a crucial effect onto the valence shell structure of sulfur. The expansion of Auger line widths was attributed to the Coster-Kronig transitions in L shells which are energetically possible. (C) 2018 Elsevier B.V. All rights reserved.