SYNTHESIS AND CHARACTERIZATION OF THE FREE LIGAND 5,6/13,14-DIBENZO-9,10-BENZO(15-CROWN-5)-2,3-BIS(HYDROXYIMINO)-7,12-DIOXO-1,4,8,11-TETRAAZACYCLOTETRA-DECANE AND ITS MONO AND TRI NUCLEAR-COMPLEXES

GOK Y., KANTEKIN H., ALP H., OZDEMIR M.

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, cilt.621, sa.7, ss.1237-1242, 1995 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 621 Sayı: 7
  • Basım Tarihi: 1995
  • Doi Numarası: 10.1002/zaac.19956210722
  • Dergi Adı: ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1237-1242
  • Anahtar Kelimeler: COBALT COMPLEXES, BF2+-BRIDGED MACROCYCLES, METAL-COMPLEXES, COBALT(II), PALLADIUM(II), COPPER(II), NICKEL(II), DIOXYGEN, PLATINUM(II), DERIVATIVES, MACROCYCLES, REACTIVITY
  • Karadeniz Teknik Üniversitesi Adresli: Evet

Özet

The novel (E,E)-dioxime 5,6:13,14-dibenzo-9,10-benzo(15-crown-5)-2,3-bis(hydroxyimino)-7,12-dioxo-1,4,8,11- tetraazacyclotetradecane (H(2)L) has been synthesized by the reaction of 4',5'-diaminobenzo(15-crown-5) with N,N'-bis(2-carbomethoxyphenyl)diaminoglyoxime (1). Only mononuclear Co-III and Ru-II complexes with a metal/ligand ratio of 1:2 have been isolated. The cobalt(III) complex bridged with BF2+ is achieved with H-bonded cobalt(III) complex and borontrifluoride ethyl ether complex. The reaction of BF2 bridged cobalt(III) complex with bis(benzonitril)palladium(II) chloride gives a trinuclear complex. The structures of dioxime and its complexes are proposed according to elemental analyses, H-1 and C-13-NMR, IR and mass spectral data.