Characterization of the microscale/nanoscale hierarchical microstructure of an as-cast CrMnFeNiCu high-entropy alloy with promising mechanical properties

Shim S. H., Pouraliakbar H., Minouei H., Rizi M., Fallah V., Na Y., ...Daha Fazla

JOURNAL OF ALLOYS AND COMPOUNDS, cilt.954, 2023 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 954
  • Basım Tarihi: 2023
  • Doi Numarası: 10.1016/j.jallcom.2023.170091
  • Dergi Adı: JOURNAL OF ALLOYS AND COMPOUNDS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, PASCAL, Aerospace Database, Chemical Abstracts Core, Chimica, Communication Abstracts, Compendex, INSPEC, Metadex, Public Affairs Index, Civil Engineering Abstracts
  • Karadeniz Teknik Üniversitesi Adresli: Hayır

Özet

In this study, we investigated the evolution of a hierarchical multiphase structure in an as-cast CrMnFeNiCu high-entropy alloy (HEA). Thermodynamic calculations were performed to better understand and clarify the phase transformation of CrMnFeNiCu that occurs when molten metal is cooled to lower temperatures. The as-cast structural analysis at the micron-and nanoscale, and thermodynamic calculations, revealed that the hierarchical microstructure consisted of Cr+Fe-rich body-centered cubic (BCC)+ 2 face-centered cubic (FCC) (Cr+Fe+Ni-rich FCC and Cu+Mn-rich FCC) phases, which were further strengthened by nanoscale pre-cipitates. Furthermore, transmission electron microscopy (TEM) studies revealed that the nanoscale pre-cipitates maintained coherent interfaces, a similar lattice constant, and an inverse trend of chemical composition with regard to their matrix. The micro/nanoscale hierarchically structured as-cast CrMnFeNiCu alloy exhibited exceptional mechanical properties with a yield stress of-587.5 +/- 20.3 MPa, ultimate tensile stress of-990.1 +/- 15.4 MPa, and a reasonable elongation of-28.7 +/- 4.6%. The proposed as-cast alloy exhibited superior mechanical properties compared with those of other as-cast HEAs.Crown Copyright (c) 2023 Published by Elsevier B.V. All rights reserved.