Bis(triethanolamine-N,O,O ')nickel(II) bis(saccharinate)

Topcu, Y; Andac, O; YILMAZ, VEYSEL; Harrison, WTA

doi:10.1107/s1600536801001878

Bis(triethanolamine-N,O,O ')nickel(II) bis(saccharinate)

Atıf İçin Kopyala

Topcu Y., Andac O., YILMAZ V. T., Harrison W.

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, cilt.57, 2001 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 57
Basım Tarihi: 2001
Doi Numarası: 10.1107/s1600536801001878
Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED)
Karadeniz Teknik Üniversitesi Adresli: Hayır

Özet

The structure of the title compound, [Ni(C6H15NO3)(2)](C7H4NO3S)(2), consists of a cationic [Ni(TEA)(2)](2+) and two anionic (SAC)(-) moieties (TEA is triethanolamine and SAC is the saccharinate anion). Two TEA ligands coordinate to the NiII ion through four O atoms and two N atoms acting as tridentate ligands (N,O,O') in a distorted octahedral environment, with the bond distances [d(Ni-O) = 2.078 (2) and 2.082 (2) Angstrom, and d(Ni-N) = 2.108 (2) Angstrom]. SAC anions participate in intermolecular hydrogen bonding with the hydroxyl H atoms of the TEA ligands to form a three-dimensional network.