BIS(N,N '-BIS(2-HYDROXYETHYL)ETHYLENEDIAMINE)NICKEL(II) SACCHARINATE: SYNTHESIS, CHARACTERIZATION AND CRYSTAL STRUCTURE

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Karadogan A., KARADAĞ A., YILMAZ V. T.

MACEDONIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING, cilt.34, sa.1, ss.101-104, 2015 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 34 Sayı: 1
  • Basım Tarihi: 2015
  • Doi Numarası: 10.20450/mjcce.2015.651
  • Dergi Adı: MACEDONIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED)
  • Sayfa Sayıları: ss.101-104
  • Anahtar Kelimeler: saccharinate, N,N '-bis(2-hydroxyethyl)ethylenediamine, nickel(II), crystal structure, COMPLEXES
  • Karadeniz Teknik Üniversitesi Adresli: Hayır

Özet

A new nickel(II) saccharinate (sac) complex containing N,N'-bis(2-hydroxyethyl)ethylenediamine (bishydeten), [Ni(bishydeten)(2)](sac)(2), has been synthesized and characterized by elemental analysis, FTIR. and single crystal X-ray diffraction. The title complex consists of a [Ni(bishydeten)(2)](2+) cation and two sac anions. In the complex cation, the nickel(II) ion is coordinated by two neutral bishydeten ligands, leading to a distorted octahedral NiN4O2 coordination, while both sac anions remain outside the coordination sphere. In the crystal, the complex cations and sac anions are connected by an extensive network of N-H center dot center dot center dot N, N-H center dot center dot center dot O, O-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds into a three-dimensional supramolecular lattice.