Synthesis and characterization of new copperphthalocyanine carrying mixed donor macrocyclic moieties


MISIR M. N. , Kantekin H. , GOEK Y., MISIR G.

JOURNAL OF COORDINATION CHEMISTRY, vol.59, no.15, pp.1667-1673, 2006 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 59 Issue: 15
  • Publication Date: 2006
  • Doi Number: 10.1080/00958970600579961
  • Title of Journal : JOURNAL OF COORDINATION CHEMISTRY
  • Page Numbers: pp.1667-1673

Abstract

The new phthalocyanine peripherally substituted with a twelve-membered dioxadiaza macrocycle was synthesized by cyclotetramerization of 1,2-bis(2-{4'-[(4'-methylphenyl)sulphonyl]- 1',7'-dioxa-4',10'-diazacyclododecane})-4,5-dicyanobenzene (4) which was obtained from 1,2-bis(2-{4'-[(4'-methylphenyl) sulphonyl]-1',7'-dioxa-4',10'-diazacyclododecane})- 4,5-dibromobenzene ( 3). Metallophthalocyanine was also prepared by the reaction of the dicyano-substituted macrocycle in the presence of anhydrous CuCN. The new compounds were characterized by a combination of elemental analysis, H-1 and C-13 NMR, IR, electronic and mass spectroscopies.