Synthesis and characterization of new copperphthalocyanine carrying mixed donor macrocyclic moieties

MISIR M. N., Kantekin H., GOEK Y., MISIR G.

JOURNAL OF COORDINATION CHEMISTRY, cilt.59, sa.15, ss.1667-1673, 2006 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 59 Sayı: 15
  • Basım Tarihi: 2006
  • Doi Numarası: 10.1080/00958970600579961
  • Dergi Adı: JOURNAL OF COORDINATION CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1667-1673
  • Karadeniz Teknik Üniversitesi Adresli: Evet

Özet

The new phthalocyanine peripherally substituted with a twelve-membered dioxadiaza macrocycle was synthesized by cyclotetramerization of 1,2-bis(2-{4'-[(4'-methylphenyl)sulphonyl]- 1',7'-dioxa-4',10'-diazacyclododecane})-4,5-dicyanobenzene (4) which was obtained from 1,2-bis(2-{4'-[(4'-methylphenyl) sulphonyl]-1',7'-dioxa-4',10'-diazacyclododecane})- 4,5-dibromobenzene ( 3). Metallophthalocyanine was also prepared by the reaction of the dicyano-substituted macrocycle in the presence of anhydrous CuCN. The new compounds were characterized by a combination of elemental analysis, H-1 and C-13 NMR, IR, electronic and mass spectroscopies.