Synthesis and characterization of new copperphthalocyanine carrying mixed donor macrocyclic moieties
JOURNAL OF COORDINATION CHEMISTRY, cilt.59, sa.15, ss.1667-1673, 2006 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 59 Sayı: 15
- Basım Tarihi: 2006
- Doi Numarası: 10.1080/00958970600579961
- Dergi Adı: JOURNAL OF COORDINATION CHEMISTRY
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.1667-1673
- Karadeniz Teknik Üniversitesi Adresli: Evet
Özet
The new phthalocyanine peripherally substituted with a twelve-membered dioxadiaza macrocycle was synthesized by cyclotetramerization of 1,2-bis(2-{4'-[(4'-methylphenyl)sulphonyl]- 1',7'-dioxa-4',10'-diazacyclododecane})-4,5-dicyanobenzene (4) which was obtained from 1,2-bis(2-{4'-[(4'-methylphenyl) sulphonyl]-1',7'-dioxa-4',10'-diazacyclododecane})- 4,5-dibromobenzene ( 3). Metallophthalocyanine was also prepared by the reaction of the dicyano-substituted macrocycle in the presence of anhydrous CuCN. The new compounds were characterized by a combination of elemental analysis, H-1 and C-13 NMR, IR, electronic and mass spectroscopies.