SYNTHESIS OF NOVEL HOMO AND HETEROBIMETALLIC COMPLEXES OF FERROCENYL FORMAZANS

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Atıf İçin Kopyala

GOK Y., TUFEKCI M., OZCAN E.

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, cilt.23, sa.5, ss.861-873, 1993 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 23 Sayı: 5
• Basım Tarihi: 1993
• Doi Numarası: 10.1080/15533179308016867
• Dergi Adı: SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Sayfa Sayıları: ss.861-873
• Karadeniz Teknik Üniversitesi Adresli: Hayır

Özet

1-(o underbar-Carboxyphenyl)-5-(p underbar-hydroxy-o underbar-carboxyphenyl)-3-ferrocenylformazan (HFF) and 1-(o underbar-carboxyphenyl)-5-(p underbar-nitro-o underbar-carboxyphenyl)-3-ferrocenylformazan (NFF) have been synthesized by the addition reaction of the diazonium salts of 2-amino-5-hydroxybenzoic acid, 2-amino-5-nitrobenzoic acid and ferrocenaldehyde-2-carboxyphenylhydrazone. The Ni(II), Pd(II), and Fe(II) complexes of HFF and NFF have also been obtained. The structures of formazans and their transition metal complexes were confirmed by elemental analyses, H-1 and C-13-NMR, IR and UV-VIS. spectral data.