Development of lauryl alcohol-impregnated cenosphere for thermal energy storage and thermal comfort enhancement in cement composites for sustainable building envelopes


Gencel O., GÜLER O., Ustaoğlu A., SARI A., Erdoğmuş E., HEKİMOĞLU G., ...Daha Fazla

Construction and Building Materials, cilt.505, 2025 (SCI-Expanded, Scopus) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 505
  • Basım Tarihi: 2025
  • Doi Numarası: 10.1016/j.conbuildmat.2025.144794
  • Dergi Adı: Construction and Building Materials
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Compendex, INSPEC
  • Anahtar Kelimeler: Cenosphere, Energy and energy efficiency, Lightweight concrete, Phase change material, Thermal energy storage
  • Karadeniz Teknik Üniversitesi Adresli: Evet

Özet

The construction and application of PCMs have been extensively investigated in cement-based ceramics, but weaknesses like leakage, instability, and low strength still exist. Conventional porous careers are of very limited improvement. This work results in a new shape-stabilized PCM structure to be developed with lauryl alcohol (LOH)-impregnated cenospheres (CS/LOH), the latter system is a design using CS/LOH. The very high LOH load enhances the latent heat holding and leakage resistance, enabling effective passive thermal management in cement composites. The CS/LOH composite was prepared through vacuum-assisted impregnation, with LOH loading to maximize up to 35 wt%, and good shape stability and thermal resistance were confirmed by FTIR, SEM-EDS, TGA and DSC analyses. The inclusion of CS/LOH in cement composites led to a 36 % reduction in dry unit weight, and a 48 % reduction in thermal conductivity. Outdoor full-scale testing showed the PCM-modified specimens effectively dampened the temperature fluctuations. The PCM-enhanced cabin prevented such heat build-up and maintained the cabin temperature up to −1.3 °C lower than outside. Cooling phases showed the cabin's temperature constantly 1.5 °C higher indoors than outdoors, indicating effective delay in overheating and improvement of indoor comfort. The surface temperature varied from + 2.6 °C to −3.5 °C. Indeed, the whole LOH-impregnated CS is an effective, lightweight material that enhances significantly energy savings and thermal comfort within building envelope.