Treatment of cyanide effluents by oxidation and adsorption in batch and column studies

YAZICI E. Y., DEVECİ H., ALP İ.

JOURNAL OF HAZARDOUS MATERIALS, cilt.166, ss.1362-1366, 2009 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 166
  • Basım Tarihi: 2009
  • Doi Numarası: 10.1016/j.jhazmat.2008.12.050
  • Dergi Adı: JOURNAL OF HAZARDOUS MATERIALS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1362-1366
  • Anahtar Kelimeler: Cyanide removal, Air oxidation, Adsorption, Activated carbon, Environment, FIXED-BED REACTOR, ACTIVATED CARBON, AIR OXIDATION, CATALYTIC-OXIDATION, AQUEOUS-SOLUTIONS, REMOVAL, WATER, DESTRUCTION, TAILINGS
  • Karadeniz Teknik Üniversitesi Adresli: Evet

Özet

In this study the removal of free cyanide from aqueous solutions by air oxidation and adsorption was investigated. Effects of air and pure oxygen, and catalyst on the rate and extent of the removal of cyanide were studied. It was found that the oxidative removal of cyanide by air/oxygen was very limited although it tended to improve in the presence of pure oxygen and catalyst such as activated carbon (AC) and copper sulphate. In the presence of continuous aeration, the non-oxidative removal of cyanide was correlated with a decrease in pH effected apparently by the transfer of carbon dioxide from air phase into the medium. The removal of cyanide by adsorption on activated carbon, nutshell (NS) and rice husk (RH) was also examined. Adsorption capacity of activated carbon was shown to be significantly enhanced via impregnation of activated carbons with metals such as copper (AC-Cu) and silver (AC-Ag). In the column tests, the breakthrough capacity of adsorbents was found to be in an increasing order of RH < AC < AC-Cu << AC-Ag. (C) 2008 Elsevier B.V. All rights reserved.