Synthesis and characterization of metal-free and metallophthalocyanines containing four 17-membered dioxa-triaza macrocycles


Yildiz S., Gok Y.

NEW JOURNAL OF CHEMISTRY, cilt.22, ss.1365-1369, 1998 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 22 Konu: 12
  • Basım Tarihi: 1998
  • Doi Numarası: 10.1039/a802353k
  • Dergi Adı: NEW JOURNAL OF CHEMISTRY
  • Sayfa Sayıları: ss.1365-1369

Özet

The synthesis and characterization of novel metal-free (8) and metal-containing (Cu, Ni or Co, 6, 9, 10) derivatives of a symmetrically tetrasubstituted phthalocyanine derived from 17,18-dicyano-4,8,12-tri(toluene-p-sulfonyl)-1,2,3,4,5,6,7,8,9,10,1 1,12,13,14,15-pentadecahydrobenzo[1.15]dioxa[4.8.12]tetraazacycloheptadecine (7), which was synthesized in a multi-step reaction sequence, have been described. The N-tosylated derivatives are highly soluble in common organic solvents. The new compounds have been characterized by elemental analyses, H-1 and C-13 NMR, IR, UV/VIS and MS spectral data.