Synthesis and characterization of a novel quinoxaline-substituted vic-dioxime and its complexes containing bis(12-diazacrown-4) derivatives

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Bilgin A., Ertem B., Goek Y.

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, vol.80, no.8, pp.1549-1555, 2007 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 80 Issue: 8
  • Publication Date: 2007
  • Doi Number: 10.1246/bcsj.80.1549
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.1549-1555
  • Karadeniz Technical University Affiliated: Yes


A new quinoxaline-substituted vicinal dioxime ligand containing bis(12-diazacrown-4) units (H2L) was synthesized by the reaction of cyanogen di-N-oxide with compound 4. Mononuclear Ni-II and Cull complexes with a metal: ligand ratio of 1:2 for HA and a trinuclear Cull complex were also synthesized. The mononuclear Cull species coordinated to two Cull ions through the deprotonated oximate oxygens to yield a trinuclear structure cis-bridged by the oximate groups, with 1, 1 0-phenanthroline as an end-cap ligand. The mononuclear Co-III complex of HA was isolated with pyridine and chlorine as axial ligands. In addition, a Co-III complex containing the BF2+ bridge macrocycle was synthesized using a precursor hydrogen-bridged Co-III complex via a template effect. The extraction abilities of 1, 3, and 11 were also evaluated in 1,2-dichloroethane by using several alkali (Li+, Na+, K+, and Cs+) and tran sition -metal picrates, such as Ag+, Pb2+, Cd2+, Cu2+, and Zn2+, Structures of the ligands and metal complexes were solved by elemental analyses, H-1 and (CNMR)-C-13, FT-IR, UV-vis, and mass spectra.