Microwave-assisted synthesis and characterization of new soluble metal-free and metallophthalocyanines substituted with four tetrathiamacrocycles through oxy bridges


BIYIKHOGLU Z., ACAR İ., KANTEKİN H.

INORGANIC CHEMISTRY COMMUNICATIONS, vol.11, no.6, pp.630-632, 2008 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 11 Issue: 6
  • Publication Date: 2008
  • Doi Number: 10.1016/j.inoche.2008.02.030
  • Journal Name: INORGANIC CHEMISTRY COMMUNICATIONS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.630-632
  • Keywords: tetrathiamacrocycles, metallophthalocyanine, synthesis, microwave, phthalonitrile, ELECTROCHEMICAL PROPERTIES, PHTHALOCYANINES, MACROCYCLES, COMPLEXES, IRRADIATION, DERIVATIVES, CHEMISTRY, NICKEL
  • Karadeniz Technical University Affiliated: Yes

Abstract

The new soluble metal-free and Ni(II), Zn(II), Co(II), Cu(II), Pb(II) phthalocyanines with four, tetrathiamacrocycles were obtained from 4-[(11-hyroxy-1,5,9,13-tetrathiacyclohexadecan-3-yl)oxy]phthalonitrile 3 and the corresponding divalent metal salt (NiCl(2), Zn(CH(3)COO)(2), CoCl(2), CuCl(2) and PbO). Metal-free and metallophthalocyanines showed the enhanced solubility in organic solvents. The structures of the target compounds were confirmed using elemental analysis, IR, (1)H NMR, (13)C NMR, UV-vis and MS spectral data. (C) 2008 Elsevier B.V. All rights reserved.