Solvent extraction of heavy metals with a 23-membered macrocyclic ionophore attached with BF2+-capped cobalt(III) complex
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, vol.43, pp.175-178, 2002 (SCI-Expanded, Scopus)
- Publication Type: Article / Article
- Volume: 43
- Publication Date: 2002
- Doi Number: 10.1023/a:1021292111325
- Journal Name: JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
- Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Page Numbers: pp.175-178
- Karadeniz Technical University Affiliated: Yes
Abstract
A new (E, E)-dioxime cobalt(III) complex [Co(HL)(2)pyCl] containing four 23-membered macrocyclic ionophores has been prepared. The cobalt(III) complex [Co(LBF2)(2)pyCl] bridged with BF2+ was prepared using the precursor cobalt(III) complex and boron trifluoride ethyl ether complex. The solvent extraction of heavy metal cations such as Ni2+, Cu2+, Zn2+, Hg2+ and Pb2+ by the BF2+-capped cobalt(III) complex has been investigated. The structure of the complexes is proposed according to elemental analyses, H-1 and C-13-NMR, IR and mass spectral data.