Synthesis and characterisation of new metallophthalocyanines containing four 12-membered diazadithia-macrocyclic moieties

Kaya E. C., KANTEKİN H., Kaya A. A., DAKOGLU A., OKSUZ S., SISIK H.

JOURNAL OF CHEMICAL RESEARCH, sa.11, ss.657-659, 2012 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: Sayı: 11
  • Basım Tarihi: 2012
  • Doi Numarası: 10.3184/174751912x13472922835683
  • Dergi Adı: JOURNAL OF CHEMICAL RESEARCH
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.657-659
  • Karadeniz Teknik Üniversitesi Adresli: Evet

Özet

Tetrasubstituted zinc, cobalt, nickel, copper and lead phthalocyanines bearing four 12-membered diazadithia macrocyclic moieties on peripheral positions have been synthesised by cyclotetramerisation reaction of 1,10-ditosyl-1,2,3,5,6,8,9,10-octahydrobenzo[h][1,4,7,10]dithiadiazacyclododecine-12,13-dicarbonitrile and corresponding anhydrous metal salts under microwave irradiation. The thermal stabilities of the phthalocyanine compounds have determined by thermogravimetric analysis.