Synthesis and characterisation of new metallophthalocyanines containing four 12-membered diazadithia-macrocyclic moieties


Kaya E. C. , KANTEKİN H. , Kaya A. A. , DAKOGLU A., OKSUZ S., SISIK H.

JOURNAL OF CHEMICAL RESEARCH, ss.657-659, 2012 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: Konu: 11
  • Basım Tarihi: 2012
  • Doi Numarası: 10.3184/174751912x13472922835683
  • Dergi Adı: JOURNAL OF CHEMICAL RESEARCH
  • Sayfa Sayıları: ss.657-659

Özet

Tetrasubstituted zinc, cobalt, nickel, copper and lead phthalocyanines bearing four 12-membered diazadithia macrocyclic moieties on peripheral positions have been synthesised by cyclotetramerisation reaction of 1,10-ditosyl-1,2,3,5,6,8,9,10-octahydrobenzo[h][1,4,7,10]dithiadiazacyclododecine-12,13-dicarbonitrile and corresponding anhydrous metal salts under microwave irradiation. The thermal stabilities of the phthalocyanine compounds have determined by thermogravimetric analysis.