Synthesis and characterisation of new metallophthalocyanines containing four 12-membered diazadithia-macrocyclic moieties
JOURNAL OF CHEMICAL RESEARCH, no.11, pp.657-659, 2012 (SCI-Expanded, Scopus)
- Publication Type: Article / Article
- Volume: Issue: 11
- Publication Date: 2012
- Doi Number: 10.3184/174751912x13472922835683
- Journal Name: JOURNAL OF CHEMICAL RESEARCH
- Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Page Numbers: pp.657-659
- Karadeniz Technical University Affiliated: Yes
Abstract
Tetrasubstituted zinc, cobalt, nickel, copper and lead phthalocyanines bearing four 12-membered diazadithia macrocyclic moieties on peripheral positions have been synthesised by cyclotetramerisation reaction of 1,10-ditosyl-1,2,3,5,6,8,9,10-octahydrobenzo[h][1,4,7,10]dithiadiazacyclododecine-12,13-dicarbonitrile and corresponding anhydrous metal salts under microwave irradiation. The thermal stabilities of the phthalocyanine compounds have determined by thermogravimetric analysis.