CHEMICAL EFFECTS ON K-BETA/K-BETA X-RAY-INTENSITY RATIOS IN COORDINATION-COMPOUNDS OF SOME 3D ELEMENTS


KUCUKONDER A., SAHIN Y., BUYUKKASAP E., KOPYA A.

JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, vol.26, no.1, pp.101-105, 1993 (SCI-Expanded) identifier identifier

Abstract

The effects of changes in coordination number on Kbeta/Kalpha x-ray intensity ratio have been studied experimentally. The Kbeta/Kalpha x-ray intensity ratios for both pure Cr, Mn and Cu and their various chemical compounds with tetrahedral and octahedral symmetry are investigated using a Ge(Li) detector. The measured results indicate that the Kbeta/Kalpha ratios for compounds with tetrahedral symmetry are in general larger than those with octahedral symmetry. The obtained Kbeta/Kalpha x-ray intensity ratios are comparable with both previous published experimental and theoretical results.