Synthesis and characterization of a novel diloop macrocycle substituted phthalocyanine


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Kantekin H. , Degirmencioglu I. , Gok Y.

ACTA CHEMICA SCANDINAVICA, vol.53, no.4, pp.247-252, 1999 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 53 Issue: 4
  • Publication Date: 1999
  • Doi Number: 10.3891/acta.chem.scand.53-0247
  • Title of Journal : ACTA CHEMICA SCANDINAVICA
  • Page Numbers: pp.247-252

Abstract

The novel metal-free and nickel phthalocyanines substituted peripherally with four 20-membered diazatetraoxa macrocycles each attached to a 15-membered crown ether moieties, have been synthesized in a multi-step reaction sequence. N-Tosylated derivatives are soluble in common organic solvents. The new compounds have been characterized by elemental analyses and by mass, IR, H-1 and C-13 NMR and UV-VIS spectroscopies.