Reactive NiO Thin Film Coating Application with DC Magnetron Sputtering Method


Turhal M.

6th INTERNATIONAL CONFERENCE ON GLOBAL PRACTICE OF MULTIDISCIPLINARY SCIENTIFIC STUDIES, Lisbon, Portugal, 9 - 16 April 2024, vol.1, pp.1800-1812, (Full Text)

  • Publication Type: Conference Paper / Full Text
  • Volume: 1
  • Doi Number: 10.5281/zenodo.1121170
  • City: Lisbon
  • Country: Portugal
  • Page Numbers: pp.1800-1812
  • Karadeniz Technical University Affiliated: Yes

Abstract

This study is about the application of reactive NiO thin film coating on glass substrate by DC

Magnetron Sputtering method. NiO finds application in ferromagnetic materials, p-type

transparent conductive film, electrochromic imaging devices and chemical sensors as a

functional sensor layer. Sputtering is a physical vapor deposition method used to deposit thin

films. This method involves sputtering material from a “target” one of which is the source, onto

a “substrate” such as glass. Sputtering is widely used in the semiconductor industry to deposit

thin films of various materials in integrated circuit processing. For optical applications, thin

anti-reflective coatings are also deposited on glass by sputtering. One of the oldest commercial

applications of the sputtering method is in the production of computer hard disks. Due to the

low substrate temperatures used, sputtering is an ideal method to deposit contact metals in thin-

film transistor fabrication. In reactive sputtering, particles sputtered from the target material

(Ni) undergo a chemical reaction aimed at the deposition of a film of different composition on

a specific substrate (glass). The chemical reaction that the particles are exposed to occurs with

a reactive gas such as oxygen supplied to the sputtering chamber, resulting in the production of

oxide films. The introduction of an additional element in the method, namely reactive gas, has

a significant impact on the desired thin film deposition and makes it difficult to find ideal

operating points. In this way, the vast majority of reactive sputtering processes are characterized

by a hysteresis-like behavior, thus requiring appropriate control of the additional inert gas,

pressure and temperature parameters involved. The existence of many parameters controlling

thin film deposition by reactive sputtering makes this a complex process, but also provides a

large degree of control over the growth and microstructure of the resulting thin film. In this

study, Oxygen (reactive gas) mixed with Argon gas in different proportions was used to produce

NiO thin film in the presence of high purity Ni target as the target. The characterization of NiO

thin films produced by keeping the pressure, temperature and plasma current limit constant was

optimized by measuring optical transmittance, reflectance, coating thickness and conductivity.