K shell X-ray fluorescence parameters of Co, Ni, Cu and Zn in phthalocyanine complexes

Dogan M., Cengız E., Dilber G., Nas A., Tıraşoğlu E., Kantekin H.

RADIATION PHYSICS AND CHEMISTRY, cilt.101, ss.30-35, 2014 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 101
  • Basım Tarihi: 2014
  • Doi Numarası: 10.1016/j.radphyschem.2014.03.024
  • Dergi Adı: RADIATION PHYSICS AND CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.30-35
  • Anahtar Kelimeler: Chemical effect, Charge transfer, Cross-sections, Intensity ratios, Ultra-LEGe detector, PRODUCTION CROSS-SECTIONS, ALPHA INTENSITY RATIOS, RADIATIVE AUGER RATIOS, EMISSION SPECTRA, BETA, FE, ELEMENTS, YIELDS, CR, PROTON
  • Karadeniz Teknik Üniversitesi Adresli: Evet

Özet

The influence of the chemical effects on sigma(K alpha,beta) production cross-sections and K-beta/K-alpha intensity ratios of Co, Ni, Cu and Zn elements in the phthalocyanine complexes was investigated. The samples were excited by 59.5 keV gamma-rays from an Am-241 annular radioactive source. K X-rays emitted by the samples were counted by an Ultra-LEGe detector with a resolution of 150 eV at 5.9 keV. We observed the effects of different ligands on the sigma(K beta) production cross-sections and the K-beta/K-alpha intensity ratios. These effects were interpreted according to the charge transfer process from the central atoms to the ligands. (C) 2014 Elsevier Ltd. All rights reserved.