Highly sensitive fluorometric method based on nitrogen-doped carbon dot clusters for tartrazine determination in cookies samples


Gumrukcuoglu A., Basoglu A., KOLAYLI S., Ding S., KARA M., OCAK M., ...Daha Fazla

TURKISH JOURNAL OF CHEMISTRY, cilt.44, sa.1, ss.99-114, 2020 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 44 Sayı: 1
  • Basım Tarihi: 2020
  • Doi Numarası: 10.3906/kim-1903-28
  • Dergi Adı: TURKISH JOURNAL OF CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core, TR DİZİN (ULAKBİM)
  • Sayfa Sayıları: ss.99-114
  • Anahtar Kelimeler: Carbon dot, amorphous, fluorescence, tartrazine, determination method, cookie, PERFORMANCE LIQUID-CHROMATOGRAPHY, QUANTUM DOTS, GREEN SYNTHESIS, SYNTHETIC DYES, NANOPARTICLES, EXTRACTION, FOODSTUFFS, DRINKS, ION
  • Karadeniz Teknik Üniversitesi Adresli: Evet

Özet

Nitrogen-doped carbon nanodots (CDs) were prepared via the solvothermal method, using urea and triethylene glycol as the starting materials. The as-prepared CDs had individual diameters of approximately 100 nm and were in clusters of different sizes. The surface composition and optical properties of the as-prepared CDs were characterized. They exhibited multicolor emission properties in the visible range when excited with a wide wavelength range. The aqueous solution of the CDs was used in highly sensitive tartrazine determination. The fluorescence quenching of the CDs was in a linear relationship with the concentrations of tartrazine in the range of 0.5-30.0 mu M. The detection limit of the assay was 0.18 mu M. Acceptable recovery results were obtained via spike-recovery experiments on cookie samples.