The Synthesis of 1,3-Thiazolium Ionic Liquids Combined with 1,2,4-Triazole-5-One by Different Synthetic Pathways

Kilinc G. G., SANCAK K.

LETTERS IN ORGANIC CHEMISTRY, vol.18, no.12, pp.1012-1024, 2021 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 18 Issue: 12
  • Publication Date: 2021
  • Doi Number: 10.2174/1570178618666210509024404
  • Journal Name: LETTERS IN ORGANIC CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Chemical Abstracts Core
  • Page Numbers: pp.1012-1024
  • Keywords: Green chemistry, triazole, thiazole, thiazolium, ionic liquid, NMR, STETTER REACTION, TEMPERATURE, THIAZOLIUM, ALDEHYDES, ELECTROLYTE, CATALYSIS, BATTERY, POLYMER
  • Karadeniz Technical University Affiliated: Yes

Abstract

Ionic liquids (ILs) are essential in green chemistry. In this study, we have synthesized and characterized novel ILs that have two heterocyclic ring systems. IL is synthesized by two different synthetic pathways. The first synthetic pathway is method A that consists of two steps. The first step of reactions involved the synthesis of IL with 1,3-thiazole ring systems, followed by the second step synthesis of 1,3-thiazole and 1,2,4-triazole-5-on ring systems. The second synthetic pathway is method B that consists of three steps. IL was synthesized by both methods A and B to confirm that the FT-IR, 1H-NMR, C-13-NMR, and Mass analysis was performed on the chemical structures.