Synthesis, Crystal Structure, Magnetic, Thermal and Fluorescent Properties of [Co(H2O)(4)(nia)(2)](suc)center dot(H(2)suc)

DEMİR S., YILMAZ V. T., Mrozinski J., Lis T., Holynska M.

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, cilt.65, sa.6, ss.695-700, 2010 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 65 Sayı: 6
  • Basım Tarihi: 2010
  • Doi Numarası: 10.1515/znb-2010-0605
  • Dergi Adı: ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.695-700
  • Anahtar Kelimeler: Succinate Complexes, Nicotinamide, Crystal Structure, Thermal Analysis, Magnetic Interaction, COORDINATION POLYMERS, ALIPHATIC DICARBOXYLATES, SUCCINIC ACID, ARCHITECTURES, NICOTINAMIDE, COBALT(II), COMPLEXES, LIGAND, PHEN=1,10-PHENANTHROLINE, PHENANTHROLINE
  • Karadeniz Teknik Üniversitesi Adresli: Hayır

Özet

A new cobalt(II) complex, [Co(H2O)(4)(nia)(2)](suc)center dot(H(2)suc) [nicotinamide = nia, succinate = suc(2-)], has been synthesized and characterized by elemental analysis, IR. TG-DTA and single-crystal X-ray diffraction. It contains [Co(H2O)(4)(nia)(2)](2+) complex cations, uncoordinated suc(2-) anios and H(2)suc species. In the complex cation the cobalt(H) ion is coordinated by four aqua and two nia ligands in a distorted octahedral geometry. The suc(2-) dianion acts as a counter-ion, while H(2)suc is present as a molecule of solvation. A three-dimensional network is formed by O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds. The title complex exhibits luminescence in the solid state at room temperature. The magnetism of the complex was studied over the temperature range 1.8 - 300 K.