JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol.693, no.3, pp.505-509, 2008 (SCI-Expanded)
Article / Article
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Science Citation Index Expanded (SCI-EXPANDED), Scopus
phthalocyanine, dithiadiazamacrocycle, phthalonitrile, macrocyclization, tosylation, ASSISTED SYNTHESIS, SUBSTITUTED PHTHALOCYANINES, INCLUSION COMPLEXES
Karadeniz Technical University Affiliated:
The novel tetrasubstituted metal-free phthalocyanine (5) and metallophtalocyanines (6, 7 and 8) bearing four 19-membered dithiadiazadioxa macrocyclic moieties on peripheral positions have been synthesized by cyclotetramerization reaction of phthalonitrile derivative (4) in a multi-step reaction sequence. The new compounds were characterized by a combination of IR, H-1 NMR, C-13 NMR, UV-Vis, elemental analysis and MS spectral data. (C) 2007 Elsevier B.V. All rights reserved.