Ethene-trans-1,2-bis(4-pyridinium) dihydrogenphosphite and dihydrogenphosphate compounds exhibiting cooperative and directed hydrogen bonds between cations and anions: H(2)bpe(H2PO3)(2) and H(2)bpe(H2PO4)(2)center dot H2O


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YILMAZ V. T., DEMİR S., Harrison W. T. A.

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, vol.61, no.9, pp.1067-1071, 2006 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 61 Issue: 9
  • Publication Date: 2006
  • Doi Number: 10.1515/znb-2006-0904
  • Journal Name: ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Index Chemicus (IC)
  • Page Numbers: pp.1067-1071
  • Keywords: dihydrogenphosphites, dihydrogenphosphates, ethene-trans-1,2-bis(4-pyridinium) cations, hydrogen bonds, crystal structure, AMINE PHOSPHATES, ZINC PHOSPHATE, FRAMEWORK
  • Karadeniz Technical University Affiliated: No

Abstract

H(2)bpe(H2PO3)(2) (1) and H(2)bpe(H2PO4)(2) center dot H2O (2) (H(2)bpe = ethene-trans-1,2-bis(4-pyridinium), H2PO3 = dihydrogenphosphite, and H2PO0 = dihydrogenphosphate) have been prepared and structurally characterized. In compound 1, the dihydrogenphosphite anions form dimers, with a P center dot center dot center dot P distance of 4.2073(7) angstrom, by two O-H center dot center dot center dot H hydrogen bonds, and the dimeric dihydrogenphosphite units interact with the H(2)bpe cations by way of N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds, resulting in a one-dimensional chain. The chains are held together by C-H center dot center dot center dot O interactions. In compound 2, the phosphate ions are connected by O-H center dot center dot center dot O hydrogen bonds into an unusual 2D square grid-type framework with P center dot center dot center dot P separations ranging from 4.7533(7) to 4.9506(8) angstrom. The H(2)bpe cations crosslink the dihydrogen phosphate layers by N-H center dot center dot center dot O hydrogen bonds, forming a three-dimensional supramolecular network with channels. The water molecules in compound 2 occupy these channels and make O-H center dot center dot center dot O bonds to adjacent phosphate O atoms and also O-H center dot center dot center dot O bonds to the next water O atom in the channel.