Co(II) and Fe(II) phthalocyanines: synthesis, investigation of their catalytic activity towards phenolic compounds and electrochemical behaviour

SAKA E. T., BIYIKLIOĞLU Z.

APPLIED ORGANOMETALLIC CHEMISTRY, cilt.29, sa.6, ss.392-399, 2015 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 29 Sayı: 6
  • Basım Tarihi: 2015
  • Doi Numarası: 10.1002/aoc.3304
  • Dergi Adı: APPLIED ORGANOMETALLIC CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.392-399
  • Anahtar Kelimeler: phthalocyanine, catalytic activity, phenolic compounds, cyclic voltammetry, electrochemistry, TETRA-SUBSTITUTED CO(II), COBALT PHTHALOCYANINE, METAL-FREE, SPECTROELECTROCHEMICAL PROPERTIES, IRON(II) PHTHALOCYANINE, FUNCTIONALIZED GRAPHENE, CYCLOHEXENE OXIDATION, WATER, 2,6-DI-TERT-BUTYLPHENOL, AUTOXIDATION
  • Karadeniz Teknik Üniversitesi Adresli: Evet

Özet

4-[(1-Benzylpiperidin-4-yl)oxy]-substituted cobalt(II) and iron(II) phthalocyanine complexes were synthesized and their catalytic activity towards various phenolic compounds was investigated. Converting from environmentally harmful phenolic compounds into less harmful oxidation products using phthalocyanines makes this study attractive. This catalysis is feasible and time-saving in terms of procedure and the best oxidation conditions determined. Electrochemical studies were also carried out using cyclic voltammetry and square wave voltammetry techniques. Voltammetric analyses of the synthesized phthalocyanine complexes supported their proposed structures. Copyright (c) 2015 John Wiley & Sons, Ltd.