Synthesis, electrochemical and spectroelectrochemical properties of peripherally tetra-imidazole substituted metal free and metallophthalocyanines

AKCAY H. T., BAYRAK R., DEMİRBAŞ Ü., KOCA A., KANTEKİN H., DEĞİRMENCİOĞLU İ.

DYES AND PIGMENTS, cilt.96, sa.2, ss.483-494, 2013 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 96 Sayı: 2
  • Basım Tarihi: 2013
  • Doi Numarası: 10.1016/j.dyepig.2012.09.005
  • Dergi Adı: DYES AND PIGMENTS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.483-494
  • Anahtar Kelimeler: Synthesis, Phthalocyanine, Imidazole, Electrochemistry, Spectroelectrochemistry, Soluble, IN-SITU, ELECTROCATALYTIC ACTIVITY, HYDROGEN-PRODUCTION, CARBON-DIOXIDE, THIN-FILMS, PHTHALOCYANINES, COBALT, MANGANESE, COMPLEXES, REDUCTION
  • Karadeniz Teknik Üniversitesi Adresli: Evet

Özet

The synthesis and characterization of novel organosoluble peripherally tetra imidazole substituted metal-free (4), zinc(II) (5), nickel(II) (6), cobalt(II) (7), lead(II) (8) and oxo-titanium(IV) (9) phthalocyanines are described for the first time in this study. Electrochemical and spectroelectrochemical measurements exhibit that while copper phthalocyanine gives only ring-based electron transfer reactions, incorporating redox active metal centers, Co(II), and Ti(IV)OPc, into the phthalocyanine core extends the redox richness of the phthalocyanine ring with the metal-based reduction and oxidation couples of the metal centers in addition to the common phthalocyanine ring-based electron transfer processes. In-situ electrocolorimetric measurements of the complexes allow quantification of color coordinates of the each electrogenerated anionic and cationic redox species. (C) 2012 Elsevier Ltd. All rights reserved.