The synthesis and characterization of a porphyrazine bearing aza-15-crown-5 moieties in the peripheral positions and its cobalt(II) complex

KANTEKİN H., CELENK E., Biyiklioglu Z., KARADENIZ H.

TRANSITION METAL CHEMISTRY, vol.33, no.2, pp.189-193, 2008 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 33 Issue: 2
  • Publication Date: 2008
  • Doi Number: 10.1007/s11243-007-9023-1
  • Journal Name: TRANSITION METAL CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.189-193
  • Karadeniz Technical University Affiliated: Yes

Abstract

The synthesis of novel metal-free (H-2-Pz) and metalloporphyrazines (MgPz and CoPz), peripherally substituted with eight aza-15-crown-5 moieties, is described. The novel compounds were characterized by elemental analysis, i.r, H-1 and C-13-n.m.r, UV-vis and m.s. spectral data.