Utilizing biomass-derived activated carbon hybrids for enhanced thermal conductivity and latent heat storage in form-stabilized composite PCMs


HEKİMOĞLU G.

ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS, cilt.46, sa.1, ss.11395-11412, 2024 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 46 Sayı: 1
  • Basım Tarihi: 2024
  • Doi Numarası: 10.1080/15567036.2024.2390112
  • Dergi Adı: ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, ABI/INFORM, Aerospace Database, Agricultural & Environmental Science Database, Applied Science & Technology Source, CAB Abstracts, Communication Abstracts, Compendex, Computer & Applied Sciences, Environment Index, Greenfile, INSPEC, Metadex, Pollution Abstracts, Veterinary Science Database, Civil Engineering Abstracts
  • Sayfa Sayıları: ss.11395-11412
  • Karadeniz Teknik Üniversitesi Adresli: Evet

Özet

In this study, the focus was on developing multifunctional organic form-stabilized composite phase change materials (PCMs) to efficiently manage thermal energy and promote sustainable energy utilization. The novel composite PCMs were designed and synthesized by incorporating Methyl stearate (MtS) as the PCM with pristine activated carbon derived from coconut shells (CAC) and thermally enhanced CAC@Graphene nanoplatelets (GnP) hybrid matrices. Particularly, the combination of CAC90@GnP10/MtS allowed the composite PCM to exhibit excellent thermophysical responses, capitalizing on the unique properties and synergistic effects of each component. The resulting composite PCM from this combination demonstrated remarkable performance, with a high loading ratio of 70% and a latent heat of 160.87 J/g, which is 27.52% higher than that of the pristine CAC-supported PCM. The test results indicated that the chemical and crystal structure of MtS remained unaffected after the composite formation. The thermal conductivity of CAC90@GnP10/MtS was found to be 102.85% higher than CAC/MtS and 195.83% higher than MtS alone. The enhancement in thermal conductivity was further validated through observed reductions in melting and solidification times, as well as analysis using infrared thermal imaging. In conclusion, the development of these intelligent, multifunctional composite PCMs, which utilize CAC@GnP hybrids as supporter scaffolds and thermal conductivity enhancers for MtS, holds great promise for effective sustainable energy usage and thermal energy management systems in various fields like waste heat utilization, energy-saving buildings, constant temperature protection, thermal management of electronic devices, aerospace industry, textiles, automotive, and renewable energy systems.