The synthesis and characterization of new metal-free and metalloporphyrazine containing macrobicyclic moieties

KARADENIZ H., GOK Y., Kantekin H.

DYES AND PIGMENTS, vol.75, no.2, pp.498-504, 2007 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 75 Issue: 2
  • Publication Date: 2007
  • Doi Number: 10.1016/j.dyepig.2006.06.027
  • Journal Name: DYES AND PIGMENTS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.498-504
  • Karadeniz Technical University Affiliated: Yes


The synthesis and characterization of new metal-free (8) and metal derivatives of a symmetrically four substituted porphyrazines (7,9) derived from 15,18,23,26-tetraoxa-5,8-dithia-1,12-diazabicyclo[10.8.8]octacos-6-ene-6,7-dicarbonitrile (6), which were synthesized in a multi-step reaction sequence have been investigated. These compounds were prepared starting from dicyanoethylene containing macrobicycle which contains sulfur, oxygen as well as nitrogen heteroatoms. These pigments were characterized by H-1, (13) C NMR, IR, UV-vis, mass spectrometry, microanalysis and AA spectrophotometry. (C) 2006 Published by Elsevier Ltd.